| Description |
1 online resource. |
| Physical Medium |
polychrome |
| Description |
text file |
| Series |
Coordination chemistry fundamentals
|
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Coordination chemistry fundamentals series ; 1.
|
| Contents |
Intro -- Title -- Copyright -- Preface -- Author Biography -- Contents -- Section 1: Basics -- Chapter 1 What is Organometallic Chemistry -- 1.1 Organic Chemistry and Inorganic Chemistry -- 1.2 Coordination Chemistry -- 1.3 Organometallic Chemistry -- References -- Chapter 2 Basic Concepts Relating to Organometallic Complexes -- 2.1 Introduction -- 2.2 EAN Rule -- 2.3 Eighteen Electron Rule (18e Rule) -- 2.4 Electron Counting -- 2.4.1 Transition Metal -- 2.4.2 Ligand -- 2.4.3 Total Charge of the Complex -- 2.4.4 Importance of Electron Counting |
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3.3.2 Ligand Field Theory (LFT) -- 3.3.3 Reason for the Establishment of the 18e Rule -- 3.4 Reason Why a Four-coordinate d8 Complex Adopts a Square-planar Structure -- References -- Chapter 4 Carbonyl, Olefin and Phosphine Complexes -- 4.1 Introduction -- 4.2 Carbonyl Complexes -- 4.3 Olefin Complexes -- 4.3.1 Change in Oxidation State of the Metal -- 4.3.2 Substituents on the Olefin -- 4.3.3 Fluxionality: Olefin Rotational Motion -- 4.3.4 C C Double Bond Length of the Olefin -- 4.3.5 Bent Back Angle of the Olefin -- 4.4 Phosphine Complexes -- References |
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Chapter 5 Carbene Complexes -- Complexes with M C Double Bonds -- 5.1 History of Carbene Complexes -- 5.2 Properties of Carbene Complexes -- 5.3 Reactivity of Carbene Complexes -- References -- Chapter 6 Basic Reactions of Organometallic Complexes -- 6.1 Introduction -- 6.2 Oxidative Addition -- 6.2.1 Vaska's Complex -- 6.2.2 C-H Bond Activation -- 6.2.3 Orthometallation -- 6.2.4 Ease of Oxidative Addition -- 6.3 Reductive Elimination -- 6.3.1 Reductive Elimination in cis-[MR2L2] (L = Phosphine, M = Ni, Pd, Pt) -- 6.3.2 Ease of Reductive Elimination |
| Summary |
Designed for teaching, this book can be used as an introductory text for chemistry undergraduates and will also provide a bridge to more advanced courses. |
| Local Note |
eBooks on EBSCOhost EBSCO eBook Subscription Academic Collection - North America |
| Subject |
Organometallic chemistry.
|
|
Organometallic chemistry. |
| Genre/Form |
Electronic books.
|
| Added Author |
Nakazawa, Hiroshi, 1952- editor.
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Koe, Julian (Julian R.), editor.
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| Other Form: |
Print version: ORGANOMETALLIC CHEMISTRY. [Place of publication not identified] : ROYAL SOCIETY OF CHEMISTR, 2021 1839164069 (OCoLC)1223069511 |
| ISBN |
9781839164200 (electronic book) |
|
1839164204 (electronic book) |
|
9781839164217 (electronic book) |
|
1839164212 (electronic book) |
|
1839164069 |
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9781839164064 |
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