| Description |
1 online resource. |
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data file |
| Series |
Polymer Science and Technology
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Polymer science and technology.
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| Note |
Includes index. |
| Bibliography |
Includes bibliographical references and index. |
| Contents |
POLYMER RELAXATION; POLYMER SCIENCE AND TECHNOLOGY; POLYMER RELAXATION; Library of Congress Cataloging-in-Publication Data; CONTENTS; PREFACE; CHAPTER 2. POLYMERS AT SOLID INTERFACES:NUCLEAR MAGNETIC RESONANCE RELAXATIONAPPROACH; ABSTRACT; INTRODUCTION; CHOICE OF A MODEL SYSTEM AND SUITABLE TECHNIQUE; An Interesting Interface: Poly(Ethylene Oxide) Grafted on Silica; Nuclear Magnetic Resonance Technique; EFFECT OF THE DIPOLAR INTERACTION FOR PEO ANDPRINCIPLES OF NMR APPROACHES; Effect of the Molecular Weight and Relaxation Analysis; Existence of the Residual Dipolar Interaction. |
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PRINCIPLES OF NMR APPROACHESTransverse Magnetic Interaction; Effect of the Dipolar Interaction for PEO; STATIC CONFORMATION; Influence of the Grafting Ratio; Influence of the Grafting Ratio on the Relaxation Times; Interpretation of NMR Experiments in Terms of Organization of the GraftedLayers; INFLUENCE OF THE TEMPERATURE; Existence of the Temperature Transition; Behaviour at Low and High Temperature; INVESTIGATION OF THE INFLUENCE OF THE SOLVENT ON THEMOTION AND CONFORMATION; Influence of the Grafting Ratio; Effect of Molecular Weight. |
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Influence of the Temperature: Evidence for a Transition TemperatureINVESTIGATION OF RESIDUAL DIPOLAR INTERACTION; Existence of a Residual Dipolar Interaction; High Resolution in PEO Grafted on Silica: Illustrative Experiments; Measure of Residual Dipolar Interaction; Influence of the Grafting Ratio; Evolution of the Pseudo Solid Effect with Temperature; THE DEUTERIUM NMR APPROACH OF THE ANISOTROPY; Effect of the Grafting Ratio; Influence of the Temperature; INVESTIGATION OF LOCAL CHAIN DYNAMICS; MAS TECHNIQUE STUDY; Rotation Effect and Limit Linewidth Study. |
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Influence of the Grafting Ratios: Determination of the Correlation TimesSPIN LATTICE RELAXATION TIME STUDY; COMPARISON OF THE CORRELATION TIMES; CONCLUSION; REFERENCES; CHAPTER 3. ELECTROCHEMICAL RELAXATION STUDIES OFPOLYTHIOPHENES; ABSTRACT; 1. INTRODUCTION; 2. EXPERIMENTAL; 2.1. Monomers, Supporting Electrolytes and Solvents; 2.2. Electrosynthesis; 2.3. Electrochemical Techniques; 2.3.1. Potential- Scan Techniques in Stationary Solution; 2.3.2. Galvanostatic (Controlled-Current) and Potentiostatic (Controlled-Potential)Technique; 2.4. Instrumentation; 3. RESULTS AND DISCUSSION. |
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3.1. Electrosynthesis of Polythiophenes3.1.1. Polymerization Techniques and Monomer Concentration; 3.1.2. Effect of Solvent; 3.1.3. Effect of Supporting Electrolyte; 3.1.4. Effect of Temperature; 3.2. Relaxation Measurements for Plythiophenes; 3.2.1. Effect of Potential Sequence; 3.2.2. Effect of Current Density; 3.2.3. Effect of Electrolyte; 3.2.4. Effect of Solvent; 3.2.5. Effect of Temperature; 3.3. Electrosynthesis of poly(Bromothiophene-co-thiophene)[poly(BrT-co-T)]; 3.3.1. Polymerization Techniques and Monomer Concentration; 3.3.2. Effect of Solvent and Supporting Electrolyte. |
| Local Note |
eBooks on EBSCOhost EBSCO eBook Subscription Academic Collection - North America |
| Language |
English. |
| Subject |
Polymers -- Analysis.
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Polymers -- Analysis. |
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Relaxation phenomena.
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Relaxation phenomena. |
| Genre/Form |
Electronic books.
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| Added Author |
Graham, Peter J. (Peter Jason), 1967-
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Neely, Catherine M.
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| Other Form: |
Print version: Polymer relaxation Hauppauge, N.Y. : Nova Science Publishers, c2012. 9781614703815 (hardcover) (DLC) 2011022218 |
| ISBN |
9781614704041 ebook |
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161470404X |
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9781614703815 hardcover |
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1614703817 |
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9781614703815 |
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