Description |
1 online resource (xxi, 548 pages) : illustrations (some color) |
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text file |
Bibliography |
Includes bibliographical references and index. |
Contents |
1. Introduction -- 2. Homoscorpionates -- first generation -- 3. Homoscorpionates -- second generation -- 4. Heteroscorpionates -- 5. Scorpionates based on thioimidazolones as sulfur donors and related ligands -- 6. Scorpionates based on thioethers as sulfur donors -- 7. Scorpionates based on diaryl and dialkylphosphine as donors -- 8. Application -- 9. Concluding remarks. |
Summary |
Since their discovery by Swiatoslaw Trofimenko in 1967, poly(pyrazol-1-yl) borates have been considered as one of the most useful ligands in modern coordination chemistry. The term "scorpionate" has been used to describe the interchange between bidentate and tridentate coordination modes by these ligands that has been employed for the synthesis of complexes with virtually every metal in the periodic table, having applications in diverse fields ranging from homogeneous catalysis to bioinorganic chemistry. This all-inclusive reference book continues where Trofimenko's original work left off. It not only includes discussions on all new ligands reported from 1999 to date, but also introduces new ligands that have yet to be touched upon in other titles, such as scorpionates based on S donors or P donors. As such, this comprehensive volume is a "must have" for all researchers who utilize this family of molecules. |
Local Note |
eBooks on EBSCOhost EBSCO eBook Subscription Academic Collection - North America |
Subject |
Scorpionates.
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Scorpionates. |
Genre/Form |
Electronic books.
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Festschriften.
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Festschriften.
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Added Author |
Trofimenko, Swiatoslaw.
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Added Title |
Scorpionates two |
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Scorpionates 2 |
Other Form: |
Print version: Pettinari, Claudio. Scorpionates II. London, UK : Imperial College Press, ©2008 (DLC) 2008425911 |
ISBN |
1860948774 (electronic book) |
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9781860948770 (electronic book) |
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9781860948763 |
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1860948766 |
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1860948766 (Cloth) |
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