| Description |
1 online resource. |
| Physical Medium |
polychrome |
| Description |
text file |
| Series |
New developments in NMR ; No. 22
|
|
New developments in NMR ; no. 22.
|
| Bibliography |
Includes bibliographical references and index. |
| Contents |
Intro -- Title -- Copyright -- Preface -- Contents -- Part 1 -- Singlet Order and Its Properties -- Chapter 1 Long-lived States in Nuclear Magnetic Resonance: An Overview -- 1.1 Introduction -- 1.2 What Are Long-lived States? -- 1.2.1 Disconnected Eigenstates -- 1.2.2 Disconnected State Manifolds -- 1.3 Symmetry Theory of Long-lived States -- 1.3.1 The Coherent Hamiltonian and Its Symmetry -- 1.3.2 The Fluctuating Hamiltonian and Its Symmetry -- 1.3.3 The Symmetric Approximate Hamiltonian -- 1.3.3.1 Symmetric Approximation of the Coherent Hamiltonian |
|
1.3.3.2 Symmetric Approximation of the Fluctuating Hamiltonian -- 1.3.3.3 The Permutation Group of the Symmetric Approximate Hamiltonian -- 1.3.4 The Number of Long-lived States -- 1.3.5 Long-lived State Operators -- 1.4 Long-lived State NMR -- 1.4.1 Excitation -- 1.4.1.1 Thermal Magnetization -- 1.4.1.2 Hyperpolarization -- 1.4.1.3 Spin-isomer Imbalances -- 1.4.2 Filtering -- 1.4.3 Evolution -- 1.4.4 Read-out -- 1.4.5 Detection -- Acknowledgements -- References -- Chapter 2 Symmetry and Long-lived Spin Order -- 2.1 Introduction -- 2.1.1 The Concept of Symmetry -- 2.1.2 The Definition of Group |
|
2.1.3 The Group Formed by the Permutation of Three Elements -- 2.1.4 Representation of Groups, Homomorphism and Isomorphism -- 2.1.5 Reducible and Irreducible Representations -- 2.1.6 The Vanishing Integral Rule -- 2.2 Symmetry Conditions for the Existence of Long-lived Spin Orders -- 2.2.1 Spin Eigenstates -- 2.2.2 Spin Relaxation -- 2.2.3 Symmetry Classification of Nuclear Spin Operators -- 2.2.4 Spin System Definition -- 2.2.5 Symmetry of the Nuclear Spin Hamiltonian -- 2.2.5.1 Symmetry of the Coherent Hamiltonian -- 2.2.5.2 Symmetry of the Fluctuating Hamiltonian |
|
2.2.5.3 Hamiltonian Averaging over Internal Motions -- 2.3 Number of Expected Long-lived Orders -- 2.3.1 Approximations -- 2.3.2 Number of LLS and Analytical Expression in the Idealized Case -- 2.3.3 Example for a Two-spin System -- 2.3.4 Example for a Three-spin System -- 2.4 LLS Accessibility via Coherent/Incoherent Mechanisms -- 2.4.1 Example 1 -- 2.4.2 Example 2 -- 2.4.3 Example 3 -- 2.4.4 Example 4 -- 2.5 Conclusions -- References -- Chapter 3 Relaxation Theory of Long-lived Spin Order -- 3.1 Introduction -- 3.2 Longitudinal and Singlet Order -- 3.3 A Model for Nuclear Spin Relaxation |
|
3.4 Relaxation Decay Rates -- 3.5 Relaxation of Longitudinal and Singlet Order Under Different Mechanisms -- 3.5.1 Isolated Singlet Pairs -- 3.5.1.1 Intra-pair Dipole-Dipole (ipDD) Mechanism -- 3.5.1.2 Symmetric Chemical Shift Anisotropy (CSA+) Mechanism -- 3.5.1.3 Anti-symmetric Chemical Shift (CSA−) Mechanism -- 3.5.1.4 Spin Rotation (SR) Mechanism -- 3.5.2 Singlet Pairs in the Presence of a 3rd Spin -- 3.5.2.1 Out-of-pair Dipole-Dipole Mechanism (opDD) -- 3.5.2.2 Inter-molecular Dipole-Dipole (imDD) Mechanism -- 3.5.2.3 Scalar-coupling of the 2nd Kind (JSK) Mechanism |
| Summary |
A long-lived form of spin order, namely singlet order, can be prepared from nuclear spin magnetisation and this first book on the subject gives a thorough description of the various aspects that interfere in the development of the topic and details the interdisciplinary applications. |
| Local Note |
eBooks on EBSCOhost EBSCO eBook Subscription Academic Collection - North America |
| Subject |
Nuclear spin.
|
|
Nuclear spin. |
|
Nuclear magnetic resonance.
|
|
Nuclear magnetic resonance. |
|
Nuclear physics.
|
|
Nuclear physics. |
| Genre/Form |
Electronic books.
|
|
Fiction.
|
|
Fiction.
|
| Added Author |
Pileio, Giuseppe, editor.
|
| Other Form: |
Print version: 1788015681 9781788015684 (OCoLC)1110670223 |
| ISBN |
9781788019989 (electronic book) |
|
1788019989 (electronic book) |
|
9781788019972 (electronic book) |
|
1788019970 (electronic book) |
|
9781788015684 |
|
1788015681 |
|
